4.7 Article

Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-decker SMMs

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 24, Pages 2973-2975

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16543k

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Funding

  1. Natural Science Foundation of China (NSFC)
  2. Ministry of Education of China
  3. Beijing Municipal Commission of Education
  4. Fundamental Research Funds for the Central Universities
  5. University of Science and Technology Beijing
  6. State Key Laboratory of Physical Chemistry of Solid Surfaces in Xiamen University

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Correlation between molecular structures and slow relaxation of magnetization of three mixed (phthalocyaninato)(porphyrinato) dysprosium(III) double-deckers clearly reveals the effect of the sandwich-type molecular structure, in particular the twist angle, on the quantum tunneling (QT) at zero dc field of these complexes, providing the first direct evidence to the theoretical inference.

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