4.7 Article

Probing double layer structures of Au (111)-BMIPF6 ionic liquid interfaces from potential-dependent AFM force curves

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 4, Pages 582-584

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15463j

Keywords

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Funding

  1. Natural Science Foundation of China (NSFC) [21033007, 21021002, 20973144, 20973141, 20911130235]

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High quality AFM force curves are presented with detailed potential dependent layering behaviors of the ionic liquid molecules, from which charged interior and neutral exterior layers are distinguished. The electric double layer is confined within the interior layers of one to two molecular size within the potential range of up to 1 V negative of the PZC.

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