4.7 Article

Visible-light-mediated addition of α-aminoalkyl radicals generated from α-silylamines to α,β-unsaturated carbonyl compounds

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 55, Pages 6966-6968

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32745g

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Funding

  1. Grants-in-Aid for Scientific Research [24105505, 11J09130] Funding Source: KAKEN

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Visible-light-mediated addition of alpha-aminoalkyl radicals generated from alpha-silylamines to alpha,beta-unsaturated carbonyl compounds using a photoredox catalyst is developed. We also succeeded in the isolation of a silyl enol ether as a primary product of the photochemical reaction.

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