4.7 Article

Synthesis and properties of β,β-sp3-hybridized subphthalocyanine analogues

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 34, Pages 4100-4102

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30511a

Keywords

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Funding

  1. Japan Society for the Promotion of Science (JSPS) [23550040, 23350095]
  2. Ministry of Education, Culture, Sports, Science, and Technology (MEXT) [20108007]
  3. Grants-in-Aid for Scientific Research [23550040, 23350095] Funding Source: KAKEN

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A beta,beta-sp(3)-hybridized subphthalocyanine analogue, dibenzosubtriazachlorin, was synthesized, and its significantly split Q band absorptions in longer and shorter wavelength regions relative to those of subphthalocyanines were revealed. The effect of benzo-annulation to a subtriazachlorin structure on the position of the split Q bands as well as the electronic structures was also investigated.

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