4.7 Article

Metal catalyzed C(sp3)-H bond amination of 2-alkyl azaarenes with diethyl azodicarboxylate

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 78, Pages 9723-9725

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35309a

Keywords

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Funding

  1. National Natural Science Foundation of China [21072047, 21272059, 21172059]
  2. Program for New Century Excellent Talents in University of Ministry of Education [NCET-09-0122]
  3. Excellent Youth Foundation of Henan Scientific Committee [114100510012]
  4. Program for Innovative Research Team in University of Henan Province [2012IRTSTHN006]
  5. Program for Changjiang Scholars and Innovative Research Team in University [IRT1061]
  6. Excellent Youth Program of Henan Normal University

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Metal-catalyzed direct C(sp(3))-H bond amination of 2-alkyl azaarenes with N=N double bonds has been developed, which expands the scope of C(sp(3))-H bond activation reactions and provides a new access to medicinally important azaarene derivatives.

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