4.7 Article

Copper-catalyzed decarboxylative C(sp2)-C(sp3) coupling reactions via radical mechanism

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 63, Pages 7847-7849

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33203e

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Funding

  1. International S&T Cooperation Program of Jiangsu Province [BZ2010048]
  2. Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry
  3. Priority Academic Program Development of Jiangsu Higher Education Institutions
  4. Key Laboratory of Organic Synthesis of Jiangsu Province

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We have successfully developed an example of copper-catalyzed decarboxylative C(sp(2))-C(sp(3)) coupling reactions via C-H functionalization for the first time. It is noteworthy that our catalytic system is very stable, low-cost, palladium-free, ligand-free, and easily accessible.

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