4.7 Article

Palladium-catalyzed esterification of aryl halides using aryl formates without the use of external carbon monoxide

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 64, Pages 8012-8014

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33944g

Keywords

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Funding

  1. MEXT, Japan
  2. Sumitomo Foundation
  3. Grants-in-Aid for Scientific Research [23655081, 23850001] Funding Source: KAKEN

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Aryl formates are efficient carbon monoxide sources in palladium-catalyzed esterification of aryl halides. The carbonylation readily proceeds at ambient pressure without the use of external carbon monoxide to afford the corresponding esters in high yields.

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