4.7 Article

A low-cost sensitizer based on a phenolic resin for charge-transfer type photocatalysts working under visible light

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 86, Pages 10621-10623

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35751h

Keywords

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Funding

  1. KOSEF NRL program [R0A-2008-000-20068-0]
  2. KOSEF EPB center [R11-2008-052-02002]
  3. Global Frontier R&D Program on Center for Multiscale Energy System [2011-0031571]
  4. Green City Technology Flagship Program
  5. KIST [KIST-2012-2E23322]
  6. National Research Foundation of Korea [R0A-2008-000-20068-0, 2008-0060152, 2008-0062041] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)

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Phenolic resin (denoted as PR) was used as an economical sensitizer of titania to achieve efficient visible light photocatalytic activity. Through the surface complexation of PR with TiO2, we demonstrate that the complexed PR layer sensitizes TiO2 under visible light through the ligand-to-metal charge transfer (LMCT) mechanism.

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