Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 41, Pages 4944-4946Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31564e
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Funding
- FCT of Portugal
- POCI
- FEDER [PTDC/QUI-QUI/110349/2009]
- FCT [SFRH/BD/66386/2009]
- Fundação para a Ciência e a Tecnologia [SFRH/BD/66386/2009, PTDC/QUI-QUI/110349/2009] Funding Source: FCT
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A direct synthesis of bidentate cyclopentadienyl-functionalised NHC-iron(II) complexes by using imidazolium salts and commercially available Fe-3(CO)(12) is developed. These well-defined iron-NHC complexes efficiently catalyse the reduction of sulfoxides under mild conditions. Radical scavenging experiments indicate the presence of free radicals in the catalytic reaction.
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