4.7 Article

NHC-carbene cyclopentadienyl iron based catalyst for a general and efficient hydrosilylation of imines

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 1, Pages 151-153

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14403k

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Funding

  1. CNRS
  2. Rennes Metropole
  3. Ministere de la Recherche et l'Enseignement Superieur
  4. Ministere des affaires etrangeres
  5. Fundacion Gran Mariscal de Ayacucho

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A general and efficient hydrosilylation of imines catalysed by a well defined NHC-carbene cyclopentadienyl iron complex has been developed. Both aldimines and ketimines are converted to the corresponding amines under mild conditions, and under visible light activation.

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