Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 29, Pages 3500-3502Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17985g
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- Royal Society
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The first enantioselective Reformatsky-type reaction of ethyl iodofluoroacetate has been accomplished with alkyl aryl ketones. High diastereoselectivities and excellent enantioselectivities for the major diastereomer (93-95% ee) were achieved with large alkyl groups. For smaller alkyl groups the diastereoselectivities were moderate, but excellent enantioselectivities were obtained for both diastereomers (79-94% ee).
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