4.7 Article

Transition-metal-free highly chemo- and regioselective arylation of unactivated arenes with aryl halides over recyclable heterogeneous catalysts

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 14, Pages 2033-2035

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16790e

Keywords

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Funding

  1. NSFC [20803024, 20936001, 21073065]
  2. DFMEC [200805611045]
  3. FRFCU [2011ZG0009]
  4. NSF of Guangdong [S2011020002397, 10351064101000000]
  5. Guangdong provincial engineering research center for green fine chemicals
  6. program for NCETU [NCET-08-0203]

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A novel heterogeneous catalysis system using metal-organic frameworks as catalyst demonstrated excellent chemo- and regioselectivity for the direct arylation of unactivated arenes with aryl iodides/bromides without the assistance of any transition metals.

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