4.7 Article

Synthesis of electron-poor hexa-peri-hexabenzocoronenes

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 65, Pages 8066-8068

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33892k

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Funding

  1. Australian Solar Institute
  2. Australian Research Council [DP0877325]
  3. Victorian Organic Solar Cell Consortium
  4. Victorian State Government (DBI-VSA)
  5. Victorian State Government (DPI-ETIS)
  6. University of Melbourne
  7. Australian Research Council [DP0877325] Funding Source: Australian Research Council

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The oxidative cyclodehydrogenation of electron-poor arenes was achieved using DDQ-CF3SO3H resulting in hexa-peri-hexabenzocoronenes with electron withdrawing Br, F and CF3 groups. This method will lead to their expansion into a new class of electron transport materials.

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