Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 76, Pages 9480-9482Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34931k
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Funding
- Spanish Ministry of Economy and Competitiveness (MINECO/FEDER) [CTQ2010-15221, CSD2009-00050, CTQ2011-27593]
- Ramon y Cajal programme
- Juan de la Cierva programme
- DGA/FSE [E07]
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A synthon for a 14-electron Ir(III) species is described. The geometrical control exerted by the ligand system over the Ir-alkenyl intermediate in hydrosilylation of terminal alkynes precludes formation of the more thermodynamically stable beta-(E)-vinylsilane, thus affording the beta-(Z) isomer in excellent yields.
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