☆ 4.7 Article

Phosphate ligands in the gold(I)-catalysed activation of enynes

CHEMICAL COMMUNICATIONS (2012)

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Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 1, Pages 52-54

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15739f

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Categories

Chemistry, Multidisciplinary

Funding

  1. MICINN [CTQ2010-16088/BQU, CSD2006-0003]
  2. AGAUR [2009SGR47]
  3. ICIQ Foundation

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Gold(I) forms neutral complexes with binol phosphates that are unreactive in the catalytic cyclisation of enynes. Reaction in protic solvents or activation by silver(I) restores the catalytic activity.

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