4.7 Article

High-spin versus spin-crossover versus low-spin: geometry intervention in cooperativity in a 3D polymorphic iron(II)-tetrazole MOFs system

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 33, Pages 3960-3962

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc18140a

Keywords

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Funding

  1. National Basic Research Program of China (973 Program) [2012CB821700]
  2. MOE of China [NCET09-0089]
  3. NSFC [20801034, 21171113, 20825102]

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Reported here are three 3D metal-organic framework (MOF) polymorphs with the chemical formula [Fe-2(H(0.67)bdt)(3)]center dot xH(2)O (H(2)bdt = 5,5'-(1,4-phenylene)bis(1H-tetrazole)), all of which are constructed from similar Fe-II-tetrazole rod secondary building units (SBUs) via covalent links, but exhibit diverse spin states regulated by inter-chain cooperativity.

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