Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 67, Pages 8329-8331Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34170k
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Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [20108010, 24350069]
- NRF/MEST of Korea through the WCU Program [R31-2008-000-10010-0]
- NRF/MEST of Korea through the GRL Program [2010-00353]
- Grants-in-Aid for Scientific Research [20108010] Funding Source: KAKEN
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Efficient photocatalytic production of hydrogen peroxide (H2O2) from O-2 and oxalate has been made possible by using a 2-phenyl-4-(1-naphthyl)quinolinium ion as a robust photocatalyst in an oxygen-saturated mixed solution of a buffer and acetonitrile with a high quantum yield of 14% (maximum 50% for the two-electron process) at lambda = 334 nm and a high H2O2 yield of 93% at lambda > 340 nm.
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