Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 19, Pages 2546-2548Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16277f
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- NIGMS NIH HHS [R01 GM050781] Funding Source: Medline
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The synthesis of M-2(II) complexes (M-II=Co, Mn) with terminal hydroxo ligands has been achieved utilizing a dinucleating ligand containing a bridging pyrazolate unit and appended (neopentyl)aminopyridyl groups. Structural studies on the complexes revealed that the M-II-OH units are positioned in a syn-configuration, placing the hydroxo ligands in close proximity (ca. 3 angstrom apart), which may be a prerequisite for water oxidation.
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