Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 10, Pages 1455-1457Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15962c
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- KAUST
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The uniqueness of the rht-MOF platform, based on the singular (3,24)-connected net, allows for the facile design and synthesis of functionalized materials for desired applications. Here we designed a nitrogen-rich trefoil hexacarboxylate (trigonal tri-isophthalate) ligand, which serves to act as the trigonal molecular building block while concurrently coding the formation of the targeted truncated cuboctahedral supermolecular building block (in situ), and enhancing the CO2 uptake in the resultant rht-MOF.
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