4.7 Article

Functionalization of graphene by electrophilic alkylation of reduced graphite

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 41, Pages 5025-5027

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31181j

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Funding

  1. Deutsche Forschungsgemeinschaft (DFG) [SFB 953]
  2. Interdisciplinary Center for Molecular Materials (ICMM)
  3. European Research Council (ERC) [246622-GRAPHENOCHEM]
  4. Graduate School Molecular Science (GSMS)
  5. Cluster of Excellence 'Engineering of Advanced Materials (EAM)'

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The reaction of Na/K-reduced graphite with hexyliodide represents a new, versatile and mild approach to synthesize alkylated graphene derivatives, which were characterized by a combination of Raman spectroscopy, TEM and TGA/MS analysis.

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