4.7 Article

Stepwise construction of grid-type Cu(II)-Cd(II) heterometallic MOFs based on an imidazole-appended dipyrrin ligand

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 83, Pages 10313-10315

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35543d

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Funding

  1. Universite de Strasbourg
  2. Institut Universitaire de France
  3. International centre for Frontier Research in Chemistry (icFRC)
  4. Marie Curie Est Actions FUMASSEC Network [MEST-CET-2005-020992]
  5. C.N.R.S.
  6. Ministere de l'Enseignement Superieur et de la Recherche

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An imidazole-appended dipyrrin ligand yields, upon coordination to Cu(II) cations, a linear metallatecton that self-assembles with Cd(II) salts to afford 2D grid-type MOFs which, upon parallel stacking, lead to porous crystals offering 1D channels.

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