Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 66, Pages 8189-8191Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33308b
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- EPSRC
- Engineering and Physical Sciences Research Council [EP/F047770/1] Funding Source: researchfish
- EPSRC [EP/F047770/1] Funding Source: UKRI
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Photocatalytic CO2 reduction has been studied for two dyads with porphyrin covalently attached to rhenium tricarbonyl bipyridine moieties, and on separate components consisting of [Re(CO)(3)(Picoline)Bpy](+) and either zinc porphyrin or zinc chlorin. TONs decrease in the order: zinc porphyrin + Re > long spacer dyad > zinc chlorin + Re > short spacer dyad.
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