4.7 Article

Helicity inversion from left- to right-handed square planar Pd(II) complexes: synthesis of a diastereomer pair from a single chiral ligand and their structure dynamism

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 31, Pages 3721-3723

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc18154a

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Funding

  1. Ministry of Education, Culture, Sports, Science and Technology, Japan
  2. Japan Society for the Promotion of Science [23350029, 23111718]
  3. Japan Science and Technology Agency
  4. Grants-in-Aid for Scientific Research [23350029, 24655053] Funding Source: KAKEN

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A diastereomer pair of left- and right-handed square planar Pd(II) complexes was synthesized from a single chiral ligand as kinetic and thermodynamic products. Helicity inversion between the diastereomers occurred rapidly under thermal and microwave irradiation conditions.

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