4.7 Article

5-Iodo-1,2,3-triazolium-based multidentate halogen-bond donors as activating reagents

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 74, Pages 9299-9301

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34392d

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Funding

  1. Fonds der Chemischen Industrie (Liebig Fellowship)
  2. Deutsche Forschungsgemeinschaft (DFG)
  3. Alexander-von-Humboldt Foundation

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Bi- and tridentate polycationic halogen bond donors based on 5-iodo-1,2,3-triazolium groups have been synthesized by 1,3-dipolar cycloaddition reactions. These halogen-based Lewis acids have been evaluated as activators in a halide-abstraction benchmark reaction.

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