Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 53, Pages 6690-6692Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32927a
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Funding
- European Commission [PIEF-GA-2009-236665]
- EPSRC [EP/G062129/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/G062129/1] Funding Source: researchfish
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A novel form of mixed-linker ZIF with the RHO topology is one of four zinc-imidazolate frameworks prepared with purine and 2-nitroimidazole. In this structure the linkers order to give a large pore solid with a high pore volume and an unusual symmetry and linker orientation. It possesses extra-framework zinc imidazolate units decorating the internal surface which can be removed to give high porosity.
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