Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 94, Pages 11528-11530Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36491c
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Funding
- Deutsche Forschungsgemeinschaft (DFG) [FOR 630, KR3316/1-2]
- European Commission (FP7 project DINAMO) [245122]
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The copper-catalyzed 1,3-dipolar azide-alkyne cycloaddition (CuAAC) was used for the first time to attach a biologically active carbon monoxide delivery agent to modified nanodiamond (ND) as a highly biocompatible carrier. The [Mn(CO)(3)(tpm)](+) photoactivatable CO-releasing molecule (PhotoCORM) on the surface retained the carbon monoxide release properties of the parent compound as shown with the myoglobin assay.
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