4.7 Article

Atmospheric pressure aminocarbonylation of aryl iodides using palladium nanoparticles supported on MOF-5

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 12, Pages 1805-1807

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc16808a

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Funding

  1. Singapore-EDB-GSK Partnership for Green and Sustainable Manufacture
  2. Institute of Chemical and Engineering Sciences, Agency for Science, Technology and Research, Singapore

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An efficient amide synthesis by atmospheric pressure aminocarbonylation using palladium nanoparticles supported on MOF-5 is reported. Interestingly, only 0.5 wt% palladium loading was required to achieve high yields. The catalyst is recyclable and offers negligible palladium leaching.

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