Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 23, Pages 2897-2899Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc00082b
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Funding
- Ministry of Education, Culture, Sports, Science and Technology (MEXT) [22390001, 2365900700, 22790011]
- Grants-in-Aid for Scientific Research [22390001, 23659007, 22790011] Funding Source: KAKEN
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An alpha-chiral nitrile carbanion generated by deprotonation of enantioenriched O-carbamoyl cyanohydrin was trapped in situ with ethyl cyanoformate to give the corresponding ester derivative in 92% yield and 90 : 10 er, providing the first example of trapping of an alpha-chiral acyclic nitrile carbanion that has been considered to be very configurationally labile.
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