Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 78, Pages 9756-9758Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35165j
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Funding
- Japan-German Graduate Externship Program by JSPS
- DFG [GRK 1628]
- MEXT Japan
- Frontier Research Base for Global Young Researchers, Osaka University
- Grants-in-Aid for Scientific Research [22105013, 24108726, 24655051, 22108518] Funding Source: KAKEN
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Our group recently prepared a hybrid catalyst containing a rhodium complex, Rh(Cp)(cod), with a maleimide moiety at the peripheral position of the Cp ligand. This compound was then inserted into a beta-barrel protein scaffold of a mutant of aponitrobindin (Q96C) via a covalent linkage. The hybrid protein is found to act as a polymerization catalyst and preferentially yields trans-poly(phenylacetylene) (PPA), although the rhodium complex without the protein scaffold normally produces cis PPA.
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