4.7 Article

A stereodynamic and redox-switchable encapsulation-complex containing a copper ion held by a tris-quinolinyl basket

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 37, Pages 4429-4431

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30339f

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Funding

  1. National Science Foundation [CHE-1012146, CHE-084441]
  2. Department of the Defense, Defense Threat Reduction Agency [HDTRA1-11-1-0042]
  3. Direct For Mathematical & Physical Scien
  4. Division Of Chemistry [0844441, 1012146] Funding Source: National Science Foundation

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We investigated the coordination of Cu(I)/Cu(II) ions to chiral basket (S-3)-1. The results of both experimental and computational studies suggest the formation of a copper redox-switchable system capable of entrapping CH3CN.

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