4.7 Article

Asymmetric olefin aziridination using a newly designed Ru(CO)(salen) complex as the catalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 57, Pages 7188-7190

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc32997b

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Funding

  1. Nissan Chemical Industries, Ltd.
  2. World Premier International Research Center Initiative (WPI)
  3. Global COE Program, 'Science for Future Molecular Systems'
  4. MEXT, Japan [23245009]

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Highly enantioselective and good to high-yielding aziridination of conjugated and non-conjugated terminal olefins and cyclic olefins was achieved using a newly designed Ru(CO)(salen) complex as the catalyst in the presence of SESN3 under mild conditions.

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