4.7 Article

A reversible nanoswitch as an ON-OFF photocatalyst

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 96, Pages 11730-11732

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36408e

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Funding

  1. Deutsche Forschungsgemeinschaft
  2. Universitat Siegen

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The two states of a new nanomechanical switch were quantitatively and reversibly populated in several subsequent switching cycles using either Cu+ or cyclam as chemical inputs. State II was demonstrated to cis-trans isomerise diazastilbene upon irradiation selectively in the presence of stilbene, and even to operate as a photocatalyst.

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