Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 6, Pages 817-819Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14856g
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Funding
- Science Foundation Ireland (SFI) [RFP/08/CHE1251]
- University College Dublin
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A variety of phosphine oxides and sulfides can be efficiently converted directly to the corresponding phosphine boranes using oxalyl chloride followed by sodium borohydride. Optically active P-stereogenic phosphine oxides can be converted stereospecifically to phosphine boranes with inversion of configuration by treatment with Meerwein's salt followed by sodium borohydride.
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