4.7 Article

Effect of dissolved LiCl on the ionic liquid-Au(111) electrical double layer structure

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 82, Pages 10246-10248

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35737b

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Funding

  1. Australian Research Council [DP0986194]
  2. Deutsche Forschungsgemeinschaft (DFG) [SPP 1191-Ionic Liquids]
  3. AINSE

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The electrical double layer at ionic liquid (IL)-Au(111) interfaces is composed of alternating ion layers. Interfacial layering is markedly weaker when small amounts of LiCl are dissolved in the IL for all potential between -2.0 V and +2.0 V (vs. Pt). This means that models developed for pure IL electrical double layers may not be valid when solutes are present.

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