Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 94, Pages 11564-11566Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36238d
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Funding
- Ministry of Education, Culture, Sports, Science, and Technology, Japan [24550221, 21108002]
- Grants-in-Aid for Scientific Research [24550221, 21108001, 11J10092, 21108002, 23245029] Funding Source: KAKEN
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We herein describe the development of an efficient enantioselective catalytic system that promotes the arylation of secondary silanes. Our method involves treatment of secondary silanes and aryl iodides with a Pd-2(dba)(3)-asymmetric phosphoramidite ligand system to afford optically active tertiary silanes with good enantioselectivities.
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