4.7 Article

Understanding the regioselectivity in Scholl reactions for the synthesis of oligoarenes

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 3, Pages 377-379

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc15980a

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A short reaction sequence leads to oligoarene derivatives utilising a regioselective Scholl reaction for the unprecedented cyclisation to the mono-functionalised oligoarene under methanol elimination. Quantum-chemical investigations reveal the reason for the remarkably high regioselectivity.

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