4.7 Article

Increasing the dimensionality of cryogenic molecular coolers: Gd-based polymers and metal-organic frameworks

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 61, Pages 7592-7594

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc33485b

Keywords

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Funding

  1. MINECO [MAT2009-13977-C03, MAT2011-24284, CSD2007-00010]
  2. EC
  3. University of Granada
  4. EPRSC
  5. Engineering and Physical Sciences Research Council [EP/H006737/1] Funding Source: researchfish
  6. EPSRC [EP/H006737/1] Funding Source: UKRI

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The magnetothermal properties of a coordination polymer and a metal-organic framework (MOF) based on Gd3+ ions are reported. An equally large cryogenic magnetocaloric effect (MCE) is found, irrespective of the dimensionality. This combined with their robustness makes them appealing for widespread magnetic refrigeration applications.

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