4.7 Article

Porous organic cage crystals: characterising the porous crystal surface

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 98, Pages 11948-11950

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36602a

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Funding

  1. EPSRC [EP/H000925/1]
  2. University of Liverpool
  3. Royal Society
  4. Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
  5. EPSRC [EP/H000925/1] Funding Source: UKRI

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The characterisation of porous crystalline solids often relies on single crystal X-ray diffraction, which does not give direct information about the surface of the material. Here, crystals of a porous organic cage, CC3-R, are investigated by atomic force microscopy and shown to possess two distinct gas-solid interfaces, proving that the bulk crystal structure is preserved at the porous crystal surface.

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