4.7 Article

An imidazole-based organocatalyst designed for bulk polymerization of lactide isomers: inspiration from Nature

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 95, Pages 11695-11697

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc37061a

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Funding

  1. Wallonia Region
  2. European Commission (FSE, FEDER)
  3. National Fund for Scientific Research (F.R.S.-FNRS)
  4. Belgian Federal Science Policy Office [PAI 6/27]

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The design of an imidazole-based salt by enzyme-mimicking allowed controlling the ring-opening polymerization of L- and D-LA monomers in bulk. Kinetic study supports a bifunctional activation process only slightly different from the one occurring in Nature.

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