4.7 Article

Improved hydrogen production from formic acid on a Pd/C catalyst doped by potassium

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 35, Pages 4184-4186

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31027a

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Funding

  1. Science Foundation Ireland [06/CP/E007]
  2. Chinese Scholarship Council
  3. Science Foundation Ireland (SFI) [06/CP/E007] Funding Source: Science Foundation Ireland (SFI)

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The rate of hydrogen production from vapour-phase formic acid decomposition can be increased by 1-2 orders of magnitude by doping a Pd/C catalyst with potassium ions. Surface potassium formate and/or bicarbonate species could be involved in the rate-determining step of this reaction.

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