Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 34, Pages 4055-4057Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30873h
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Funding
- EPSRC
- University of Manchester
- University of Leeds
- EPSRC [EP/H015639/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H015639/1, GR/S12883/01] Funding Source: researchfish
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The electronic structures of [Cu(terpy)(2)](2+) and [Cu(bpp)(2)](2+) (bpp = 2,6-di[pyrazol-1-yl]pyridine) are different, when doped into [M(bpp)(2)][BF4](2) (M2+ = Fe2+ or Zn2+). The [Cu(terpy)(2)](2+) dopant is a typical pseudo-Jahn-Teller elongated copper(II) center. However, the [Cu(bpp)(2)](2+) sites show EPR spectra consistent with a tetragonally compressed {d(z2)}(1) configuration.
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