4.7 Article

Generation of diamondoid hydrocarbons as confined compounds in SAPO-34 catalyst in the conversion of methanol

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 25, Pages 3082-3084

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc17676a

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Funding

  1. National Natural Science Foundation of China [20973164, 20903091, 20906089, 21103180]

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Formation of adamantane hydrocarbons and their confinement in SAPO-34 caused the long induction period and the quick catalyst deactivation in methanol conversion. Via ship-in-a-bottle synthesis, adamantane and methyladamantanes could be produced from methanol conversion in the cage of 8-ring SAPO catalysts under very mild reaction conditions.

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