4.7 Article

Abnormal oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes: synthesis, structure, and properties

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 77, Pages 9625-9627

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc35020c

Keywords

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Funding

  1. Shanghai Pujiang Talent Program [11PJ1402500]
  2. Fundamental Research Funds for the Central Universities [WK1114014]
  3. Shanghai Municipal Committee of Science and Technology [08dj1400100-2]
  4. National Basic Research Program of China (973) [2010CB833302]
  5. National Natural Science Foundation of China [21171056, 21072206, 20472096, 20872162, 20672127, 20821002, 20732008]

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A series of new 2,3,5-triaryl-substituted oxazolium and thiazolium salts are readily prepared by a Tf2O-mediated intramolecular cyclisation and their use as precursors for the synthesis of novel oxazol-4-ylidene and thiazol-4-ylidene rhodium complexes has been developed.

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