4.7 Article

High rate delithiation behaviour of LiFePO4 studied by quick X-ray absorption spectroscopy

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 94, Pages 11537-11539

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc36382h

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Funding

  1. Northeastern Center for Chemical Energy Storage, an Energy Frontier Research Center
  2. U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences [DE-SC0001294]

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A novel in situ time-resolved synchrotron X-ray absorption spectroscopy (XAS) was introduced for the dynamic studies during fast chemical and electrochemical delithiation of LiFePO4. The lithium diffusion in LiFePO4 and the reaction mechanisms for both processes were investigated. This approach opens new opportunities for dynamic studies of various energy storage systems.

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