4.7 Article

Rational design of a NIR-emitting Pd(II) sensor via oxidative cyclization to form a benzoxazole ring

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 32, Pages 3824-3826

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc30240c

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Funding

  1. University of Akron
  2. department of chemistry
  3. Division Of Chemistry
  4. Direct For Mathematical & Physical Scien [0840446] Funding Source: National Science Foundation

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By using the substituent effect to tune the palladium(II)-involved reactivity, a new probe is found to respond quantitatively to Pd(II). Unexpectedly, the probe gave an emission band in the desirable near-infrared (NIR) region (780 nm), thus providing the first NIR sensor for palladium detection.

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