Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 43, Pages 5355-5357Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31748f
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Funding
- Japanese government [23750174]
- GCOE Education and Research Center for Emergence of New Molecular Chemistry
- Grants-in-Aid for Scientific Research [23750174] Funding Source: KAKEN
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A photosensitizer [Ru(bpy)(3)](2+) catalyzes oxidative coupling reaction of enamines with silyl enol ethers under visible light irradiation by a Xe lamp or sunlight to produce gamma-diketones. A 2e-oxidation process involved in this reaction is achieved by a combination of the photoexcited [Ru(bpy)(3)](2+) species and duroquinone, a 2e-acceptor.
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