Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 1, Pages 124-126Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cc14744g
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Funding
- Australian Research Council
- Deutscher Akademischer Austausch Dienst (DAAD)
- Australian Institute of Nuclear Science and Engineering Inc. (AINSE)
- Fonds der Chemischen Industrie
- DFG [1166]
- Australian Synchrotron, Victoria, Australia [AS101/PD2296]
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The complexes (N-4444)(3)[Ln(dcnm)(6)] (Ln = La-Nd, Sm; N-4444 = tetrabutylammonium) display a decrease in the melting point upon fast cooling from a melt, which is shown by in situ synchrotron based X-ray powder diffraction to be due to the formation of a second, less thermodynamically stable, polymorph.
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