Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 75, Pages 9376-9378Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34185a
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- Japan Society for the Promotion of Science (JSPS)
- Council for Science and Technology Policy (CRTP)
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Non-protected halohydrins are cross-coupled with aryl aluminium reagents to produce aryl alkanols in the presence of the iron-bisphosphine catalysts. Remarkable reaction rate enhancement and diastereoinduction are realized by the in situ generated aluminium alkoxides, offering a new method for the reactivity and selectivity control of the iron-catalysed cross-coupling reaction.
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