Journal
CHEMICAL COMMUNICATIONS
Volume 48, Issue 39, Pages 4689-4691Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc31212c
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Funding
- EPSRC [EP/H000925/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/H000925/1] Funding Source: researchfish
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A crystalline porous organic cage molecule, CC3, is shown to adsorb up to 20.1 wt% water reversibly. This was confirmed by both gravimetric sorption and by crystallographic analysis. Crystals of CC3 are stable in boiling water for at least 4 h. The surprising chemical and supramolecular stability of these imine-based molecular crystals suggests scope for practical applications in humid environments.
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