4.7 Article

Au25 nanocluster-catalyzed Ullmann-type homocoupling reaction of aryl iodides

Journal

CHEMICAL COMMUNICATIONS
Volume 48, Issue 98, Pages 12005-12007

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c2cc34765b

Keywords

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Funding

  1. Air Force Office of Scientific Research under AFOSR Award [FA9550-11-1-9999, FA9550-11-1-0147]
  2. NSF [CHE-0130903]

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The Au-25(SR)(18)/CeO2 nanocluster catalyst showed high activity in the homocoupling of aryl iodides (e.g. up to 99.8% yield with iodobenzene) and excellent recyclability.

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